1.

25 ml of H_(2)O_(2) solution were added to excess of acidified KI solution. The iodine so liberated required 20 ml of 0.1 N Na_(2)S_(2)O_(3) solution. Calculate strength in terms of normality and percentage.

Answer»

0.04 N, `0.136%`
0.08 N, `0.136%`
0.08 N, `0.163%`
0.02 N, `0.163%`

Solution :`O_(2)^(-)+2E^(-) rarr 2O^(-2),"" 2I^(-) rarr I_(2)+2e^(-)`
`2(S^(+2))_(2) rarr (S^(+5//2))_(4)+2e^(-), I_(2)+2e^(-) rarr 2I^(-)`
Meq. Of `H_(2)O_(2)=` Meq. of `I_(2)=` Meq. of `Na_(2)S_(2)O_(3)`
`w/(34//2) times 1000=20 times 0.1`
`therefore W_(H_(2)O_(2))=0.034 gr//25ml`
`therefore N_(H_(2)O_(2))=0.034/(34//2) times 1000/25=0.08`
Vol. STRENGTH `=5.6 times 0.08=0.448`
% strength `=17/56 times 5.6 times 0.08=0.136%`


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