1.

26.8 g of Na_2SO_4.xH_2O gave 12.6 g of water on heating. Determine the value of x in the compound using mole concept.

Answer»

Solution :Weight of hydrated salt `Na_2SO_4.xH_2O = 26.8 g`
Weight of water given by it = 12.6 g
`therefore` Weight of anhydrous salt `Na_2SO_4 = 26.8 - 12.6 = 14.2g`
Gram molecular mass of `Na_2SO_4 = (2 xx 22.99) + 32.06 + (4 xx 16.0) = 142.04 g`
`therefore` Number of moles of `Na_2SO_4 = 142 04/(142.04) = 0.0999`
and number of moles of `H_(2)O`associated with it `12.6/18.016`
`therefore 0.0999` moles of `Na_2SO_4` ATTACH moles of water = `0.699 , therefore` 1 MOLE of `Na_2SO_4` will attach moles of water
`=0.699/0.0999 xx 1`
= 6.99
=7, Hence, x=7


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