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28 mg of an organic compound containing nitrogen was digested according to Kjeldahl's method and the evolved ammonia was absored in 20 mL of 0.1 M HCl solution. The excess of the acid required 15 mL of 0.1 M NaOH solution for complete neutralization. Then the percentage of 'N' is the compound is |
Answer» <html><body><p>50<br/>30<br/>25<br/>40</p>Solution :Excess <a href="https://interviewquestions.tuteehub.com/tag/acid-847491" style="font-weight:bold;" target="_blank" title="Click to know more about ACID">ACID</a> `= 15xx0.1xx1` m. eq.<br/>Acid taken initially `= 20xx0.1xx1` m.eq.<br/>Acid used for neutralisation<br/>`=(20xx0.1xx1)-(15xx0.1xx1)=0.5` m. eq.<br/>`% <a href="https://interviewquestions.tuteehub.com/tag/n-568463" style="font-weight:bold;" target="_blank" title="Click to know more about N">N</a> =(NH_(3)" liberated"xx1.4)/("wt.of <a href="https://interviewquestions.tuteehub.com/tag/org-1138670" style="font-weight:bold;" target="_blank" title="Click to know more about ORG">ORG</a>. <a href="https://interviewquestions.tuteehub.com/tag/compound-926863" style="font-weight:bold;" target="_blank" title="Click to know more about COMPOUND">COMPOUND</a>")=(0.5xx1.4)/(0.028)=25%`.</body></html> | |