1.

3.92 g of ferrous ammonium suphate ar dissolved in 100 Ml water 20 ml of this solution requires 18 complete oxidation the weight of KMnO_(4) present in one litre of the solution is

Answer»

34.76 G
12.38 g
1.23 g
3.476 g

Solution :The redox reaction involving the oxidation of `Fe^(2+)` is
`MnO_(4)^(-)+5Fe^(2+)+8H^(+)rarr5Fe^(3+)+MN^(2+)+4H_(2)O`
Mol WT of ferrous ammonium suphate
`(NH_(4))SO_(4)FeSO_(4)6H_(23)O=392`
applyinhg molarity equation
`=(M_(2)V_(2))/(n_(2))`
or `(0.1xx20)/(5)=(M_(2)xx18)/(1)`
or `M_(2)=(0.1xx20)/(5xx18)=(M)/(45)`
Amount of `KMnO_(4)` present in one litre
=Molarity x mol wt
`1/45xx158=3.51` g
since 3.476 g isclose to 3.51 g therefore option (d) is correct


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