CARBON has FOUR covalent bond. Centre carbon is attach with other four carbon and so there is no valence for attachement of HYDROGEN `1^(@), 2^(@)` and `3^(@)` carbon are stable but `4^(@)` carbon is unstable. Free RADICAL is formed with `4^(@)` carbon.
Solution :Centre carbon is attach with other four carbon and so there is no valence for attachement of hydrogen