1.

50 ml of given H_(2)O_(2) solution is added to excess KI solution in acidic medium. The liberated I_(2) requires 20 ml of 0.04 M standard Hypo solution. Molarity of H_(2)O_(2) solution is

Answer»

`8xx10^(-3)M`
`4xx10^(-3)M`
`5XX10^(-3)M`
None of these

Solution :`2I^(-)+H_(2)O_(2)+2H^(+)rarr2H_(2)O+I_(2)`
`I_(2)+2S_(2)O_(3)^(-2)rarr2I^(-)+S_(4)O_(6)^(-2)`
Eqts of `H_(2)O_(2)` = EQ `Na_(2)S_(2)O_(3)`
`(2xx50)/(1000)xxM=(1xx20)/(1000)xx0.04impliesM=8xx10^(-3)`


Discussion

No Comment Found