1.

9.2 grams of N_(2)O_(4) (g) is taken in a closed one litre vessel and heated till the following equilibrium is reachedN_(2) O_(4) (g) hArr 2 NO_(2) (g) At equilibrium , 50% N_(2)O_(4) (g) is dissociated . What is the equilibrium constant ( in mol lit^(-1)) (" Molecular weughtof" N_(2)O_(4) = 92)

Answer»

`0.1`
`0.2`
`0.4`
2

Solution :Intial` [N_(2)O_(4)] = 9.2//92 " mol"L^(-1) = 0.1 " mol "L^(-1)`
At. Eqm. ( after 50% dissociation ),
`[N_(2)O_(4)] = 0.05 M, [NO_(2)] = 0.1 M`
` K = ([NO_(2)])/([N_(2)O_(4)])=(0.1)^(2)/0.05 = 0.2`


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