1.

A 0.01 M solution of glucose in water freezes at -0.0186^(@)C A 0.01 M solution of KNO_(3) in water will freeze at

Answer»

`-0.0093^(@)C`
`-0.0372^(@)C`
`-0.0186^(@)C`
`-0.093^(@)C`

SOLUTION :`KNO_(3)` ionises as,
`KNO_(3) HARR K^(+) + NO_(3)^(-)`
`therefore` Concentration in solution `=2xx0.01=0.02`
`DeltaT_(f)=T_(f)-T^(@)=K_(f)xxm`for glucose
`therefore k_(f)(DELTATF)/(m)=(0.018)/(0.01)=1.86^(@) m^(-1)`
`DeltaT_(f)` for `KNO_(3)=1.86xx0.02=0.0372^(@)C`
`T_(f)=T^(@)-T_(f)=0.0000-0.0372=-0.0372^(@)C`


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