A 2 lit solution contains 0.04 mol of each of [CO(NH_(3))_(5)SO_(4)]Br and [CO(NH_(3))_(5)Br]SO_(4). To 1 lit of this solution, excess of AgNO_(3) is added. To the remaining solution of excen of BaCl_(2) is added. The amounts of precipitated salts, respectively, are

A 2 lit solution contains 0.04 mol of each of [CO(NH_(3))_(5)SO_(4)]Br

1.	A 2 lit solution contains 0.04 mol of each of [CO(NH_(3))_(5)SO_(4)]Br and [CO(NH_(3))_(5)Br]SO_(4). To 1 lit of this solution, excess of AgNO_(3) is added. To the remaining solution of excen of BaCl_(2) is added. The amounts of precipitated salts, respectively, are
Answer» 0.01 mol & 0.01 mol <BR>0.01 mol & 0.02 mol 0.02 mol & 0.01 mol 0.02 mol & 0.02 mol SOLUTION :Given that 2L solution contains 0.04 mol each of `[CO(NH_(3))_(6)SO_(4)]Br and [CO(NH_(3))_(5)Br]SO_(4)`. Therefore, the concentration is 0.02 mol `"LIT"^(-1)`. `underset("0.02 mol")([CO(NH_(3))_(5)SO_(4)]Br)underset("0.02 mol0.02 mol")(rarrBr+[CO(NH_(4))_(5)SO_(4)]^(+))` `underset("0.02 mol")([CO(NH_(3))_(5)Br]SO_(4))underset("0.02 mol ")(rarrSO_(4)^(-2))+underset("0.02 mol")([CO(NH_(3))_(5)Br]^(+2))` `underset(("EXCESS"))(AG^(+))+underset((0.02))(Br^(-))rarrunderset(0.02)(AgBr)` `underset(("excess"))(Ba^(+2))+underset((0.02))(SO_(4)^(-2))rarrunderset(0.02)(BaSO_(4))`