1.

A alkayl halide with molecular formula C_(6)H_(13)Br on dehydrohalogenation gave two isomeric alkenes X and Y with molecular formula C_(6)H_(12). On reductive ozonolysis, X and Y gave four compounds CH_(3)COCH_(3), CH_(3)CHO, CH_(3)CH_(2)CHO and (CH_(3))_(2) CHCHO. Find the alkyl halide.

Answer»

Solution :(i) `C_(6)H_(13)BR` is a 3-Bromo-4 METHYLPENTANE.`CH_(3) - UNDERSET(underset(CH_(3))(|))(CH)- underset(underset(H)(|))overset(overset(Br)(|))(C) - CH_(2) - CH_(3)`
(ii) 3-Bromo-4 methylpentane on dehydrogenation GIVE two isomers X and Y as follows:

Therefore `C_(6)H_(13)Br` is 3-Bromo-4- methylpentane.


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