1.

A buffer solution contains 2 moles of ammonium hydroxide and 0.25 mole of ammonium chloride per dm^(3) of the solution. (K_(b) for ammonium hydroxide = 1.8xx10^(-5)). Calculate the pH of the buffer solution.

Answer»

Solution :It is a BASIC BUFFER
`pOH=pK_(B)+"LOG"(["Salt"])/(["Base"])`
= `4.74+"log"0.25/2=4.74+"log"0.25/2`
= 4.74 - 0.90 = 3.64
pH = 14 - 3.64
= 10.36


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