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A colourless inorganic salt (A) decomposes completely at about 250^(@)C to give only two products, (B) and (C), leaving no residue. The oxide (C) is a liquid at room temperature and neutral to moist litmus paper while the gas (B) is a neutral oxide. White phosphours burns in excess of (B) to produce a strong white dehydrating agent. Write balanced equations for the reactions involved in the above process. |
Answer» <html><body><p></p>Solution :(i) Since a colourless inorganic salt (A) on <a href="https://interviewquestions.tuteehub.com/tag/heating-1017297" style="font-weight:bold;" target="_blank" title="Click to know more about HEATING">HEATING</a> to `250^(@)C` <a href="https://interviewquestions.tuteehub.com/tag/decomposes-946040" style="font-weight:bold;" target="_blank" title="Click to know more about DECOMPOSES">DECOMPOSES</a> to form twooxides (B) and (C) leaving no residue, therefore, compound (A) must be ammonium nitrate `(NH_(4)NO_(3))`. <br/> `underset((A))(NH_(4)NO_(3))overset(250^(@)C)tounderset((B))(N_(2)O)+underset((C))(2H_(2)O)` <br/> (ii) The fact that inorganic salt (A) is actually ammonium nitrate is confirmed by the observation that oxide (C), i.e., `H_(2)O` is a liquid at room temperature. <br/> (iii) If the oxide (C) is `H_(2)O` then other neutral oxide (B) must be nitrous oxide, `N_(2)O`. <br/> (iv) The fact that the neutral oxide (B) is actually `N_(2)O` is confirmed by the observation that white phosphorus burns in `N_(2)O` to form phosphorus pentoxide which is a strong dehydrating agent. <br/> `underset("Nitrous oxide (B)")(10N_(2)O)+P_(4)tounderset("Phosphorus pentoxide")(P_(4)O_(<a href="https://interviewquestions.tuteehub.com/tag/10-261113" style="font-weight:bold;" target="_blank" title="Click to know more about 10">10</a>))+10N_(2)` <br/> Thus, inorganic salt (A) is ammonium nitrate `(NH_(4)NO_(3))`, (B) is nitrous oxide `(N_(2)O)` and (C) is water `(H_(2)O)`.</body></html> | |