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A current of 9.65 amperes is passed through three different electrolytes, i.e., `NaNO_(3), KCl` and `ZnSO_(4)` for 30 min separately. Calculate the mass ratio of the metals deposited at the respective electrodes. Also find out the weights of various metals deposited at the respective electrodes. |
Answer» Quantity of electricity passed through the electrolyte = current `xx` time of flow `= 9.65 xx 30 xx 60` coulombs `m_(Na) : m_(K) : m_(Zn) = E_(Na) : E_(K) : E_(Zn)` `{:(E_(Na) = 23/1 = 23,, (Na^(+) + e^(-) to Na)),(E_(K) = 39/1 = 39,, (K^(+) + e^(-) to K)),(E_(Zn) = 65/2 = 32.5,, (Zn^(+2) + e^(-) to Zn)):}` `m_(Na) : m_(K) : m_(Zn) = 23 : 39 : 32.5` Weight of sodium deposited `= (23 xx 9.65 xx 30 xx 60)/(96500) = 4.14 g` Weight of potassium deposited `= (39 xx 9.65 xx 30 xx 60)/(96500) = 7.02 g` Weight of zinc deposited `= (32.5 xx 9.65 xx 30 xx 60)/(96500) = 5.85 g` |
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