1.

A cylindrical balloon of 21 cm diameter is to be filled up with H_2 at NTP from a cylinder containing the gas at 20 atm " at "27^(@)C. The cylinder can hold 2.82 litre of water at NTP. Calculate the number of balloons that can be filled up.

Answer»

Solution :Volume of 1 balloon which has to be filled `=4"/"3pi (21"/"2)^(3)`
`=4851 mL=4.851` litre
LET n balloons be filled, then volume of `H_(2)` OCCUPIED by balloons `=4.851xxn`
Also, cylinder will not be empty and it will OCCUPY volume of `H_(2)= 2.82` litre.
Total volume occupied by `H_(2)" at "NTP=4.851xxn +2.82` litre
At STP
`P_(2)=1 " atm Available "H_(2)`
`V_(1)=4.851xxn+2.82""P_(2)=20 atm`
`T_(1)=273K""T_(2)=300K`
`P_(1)V_(1)"/"T_(2)=P_(2)V_(2)"/"T_(2)""V_(2)=2.82` litre
or `1xx(4.851n+2.82"/"273)=20xx2.82"/"300"":. n=10`


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