1.

A flask contains a mixture of isohexane and 3-methylpentane. One of the liquids boils at 63^(@)C while the other boils at 60^(@)C. What is the best way to separate the two liquids and which one will be distilled out first?

Answer»

Fractional distillation, ISOHEXANE
Simple distillation, 3-methylpentane
Fractional distillation, 3-methylpentane
Simple distillation, isohexane

Solution :When the difference between the B.P of the two liquids is LESS than around `40^(@)C`, fractional distillation is more efficient. The difference between the boiling points of isohexane and 3-methylpentane is only 3 degrees. So, fractional distillation is the best suitable method. Since, isohexane has a lower boiling point, it COMES out first.


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