1.

A gas described by van der Waals equation

Answer»

behaves similar to an ideal gas in the limit gas in the limit of large molar volumes
behaves similar to an ideal gas in the limit of large pressures
is characterised by van der Waals coefficients that are dependent on identity of the gas but are independent of the pressure
has the pressure that is lower than the pressure EXERTED by the same behaving ideally

Solution :van der Waals equation is
`(P+(an^(2))/(V^(2)))(V-nb)=nRT`.
(a) is correct because for large molar volumes, `an^(2)//V^(2)` is small and can be neglected in comparison to P and nb can be neglected in comparison to V. Eqn. becomes PV=nRT.
(c ) is correct because van der Waals coefficients depend only on the NATURE of the gas.
(d) is correct because due to inward pull on the MOLECULES striking the WALL, the pressure is lower.


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