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A gas described by van der Waals equation |
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Answer» behaves similar to an ideal gas in the limit gas in the limit of large molar volumes `(P+(an^(2))/(V^(2)))(V-nb)=nRT`. (a) is correct because for large molar volumes, `an^(2)//V^(2)` is small and can be neglected in comparison to P and nb can be neglected in comparison to V. Eqn. becomes PV=nRT. (c ) is correct because van der Waals coefficients depend only on the NATURE of the gas. (d) is correct because due to inward pull on the MOLECULES striking the WALL, the pressure is lower. |
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