1.

A gaseous hydrocarbon gives upon combustion 0.72 g of water and 3.08 g of CO_(2). The empirical formula of the hydrocarbon is

Answer»

`C_(7)H_(8)`
`C_(2)H_(4)`
`C_(3)H_(4)`
`C_(6)H_(5)`

Solution :Let the mass of GASEOUS HYDROCARBON taken = w gm
`:. %C = (12)/(44) xx (3.08)/(w)xx 100 = (84)/(w)`
`%H = (2)/(18)xx (0.72)/(w)xx 100 = (8)/(w)`
Ratio of C : H atoms `= (84)/(w) xx(1)/(12) : (8)/(w) xx (1)/(1) = 7 : 8`
THUS, E.F. = `C_(7)H_(8)`.


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