1.

A highly viscous compound (X) on reacting with conc. HNO_(3) gives an inorganic ester (Z) which on detonation gives CO_(2), N_(2), O_(2) as gaseous products. With KMnO_(4) it gives a compound (Y) of the molecular formula C_(2)O_(4)H_(2) which can also be obtained from glycol using same reagent. The compound (X) is

Answer»

Phenol
Glycerol
Glycollic acid
None of the above

Solution :Clearly compound (Y) is `{:(COOH),("|"),(COOH):}`
The reactions are
`{:(CH_(2)_OH),("|"),(CH-OH overset(Conc. HNO_(3))RARR underset((Z))underset("Glycerltrinitrate")(C_(3)H_(5)(ONO_(2))_(3))overset("Detonating")rarrCO_(2)+N_(2)+O_(2)+H_(2)O),("|"),(underset((X))(CH_(2)-OH)):}`


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