1.

(a) How bond energy veries fromN_(2) ^(-)toN_(2)^(+)and why ? (b) On the basis of molecular orbital theory what is similartiy between (i)F_(2), O_(2) ^(- )(ii)CO, N_(2) , NO^(+) ?

Answer»

Solution :(a) Bond energy of ` N_(2)^(+)` = Bond energy of ` N_(2)^(-)` . This is because they have the same bond order.
(Strictly SPEAKING , ` N_(2)^(-)`is SLIGHTLY less stable and hence has less bond energy then `1 N_(2)^(+)`due to presnece of
greater NUMBER of electronsin the antibonding molecular orbitals )
(b) (i) Same bond order and bond lenght . (II) Same bond order and bond length .


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