1.

A hydrated metal chloride contains 27.8%metal and 48.5% halogen by weight.Specific heat ofmetal (M) is 0.67jg^(-1) . What is the valency of the metal?

Answer»

Solution :SPECIFIC HEAT of M =0.67 `jg^(-1)` =0.16cal `g^(-1)`
ATOMIC MASS of M = 6.4/0.16=40
Relative number of M atoms `=(27.8)/(40)=0.695`
Relative number of Cl atoms `=(48.5)/(35.5)=1.37`
Ratio of number of atoms, of M and C =0.695 :1.37=1:2
FORMULA of metal chloride is `MCl_(2)`
Valency of metal is 2


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