1.

A hydrocarbon (X) was found to have a molecular weight of 80-85. A 10.02 mg sample took up 8.40mL of H_(2) gas measured at 0^(@)C and 760 mm pressure. Ozonolysis of (X) yields only HCHO and OHC-CHO. What was hydrocarbon?

Answer»

`C_(6)H_(8)`
`C_(6)H_(10)`
`C_(6)H_(12)`
`C_(6)H_(14)`

Solution :MOLES of `H_(2)` taken up
`= (8.40 xx 10^(-3))/(22.4) = 3.75 xx 10^(-4)`
Moles of compound `=(10.02 xx 10^(-3))/(22.4) = 1.254 xx 10^(-4)`
THUS, moles of `H_(2)` taken up by 1 mole of compound `=(3.75 xx 10^(-4))/(1.254 xx 10^(-4)) =3`
Therefore, molecules has three double bonds and it may be hexa-1,3,5-triene.


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