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A mixture of two gases, H_(2)S and SO_(2) is passes throgh three beakers successivly. The first beaker contains Pb^(2+) ions, which absobs all H_(2)S to form PbS. The second beaker contains 25mL of 0.0396 N I_(2). Whichocidises all SO_(2) to SO_(4)^(2-) . The thirdbeaker contains 10 mL of 0.0345 N thisulphate solutionti retainany I_(2) carried over from the second absorber. Thesolution from first absorber was made acidic and treated with 20 mL of 0.0066 M K_(2) Cr_(2) O_(7), acidic and treated with 20mL of 0.006M K_(2) Cr_(2)O_(7) which convertedS^(2-) to SO_(2). The excess dichromate was reacted with solid KIand the liberated iodine required 7.45mL of 0.0345N Na_(2)S_(2)O_(3) solution. The solution in the second andthrid absorbers were combined and the resulatantiodide was treated with 2.44 mL fo the same solution of thisulphate. Calculate the conventrations fo SO_(2) and H_(2)S in (mg)/"litre"of the sample. |
Answer» <html><body><p><br/></p><a href="https://interviewquestions.tuteehub.com/tag/answer-15557" style="font-weight:bold;" target="_blank" title="Click to know more about ANSWER">ANSWER</a> :<a href="https://interviewquestions.tuteehub.com/tag/conc-927968" style="font-weight:bold;" target="_blank" title="Click to know more about CONC">CONC</a> of `SO_(2) = 0.72mg//"<a href="https://interviewquestions.tuteehub.com/tag/litre-1075864" style="font-weight:bold;" target="_blank" title="Click to know more about LITRE">LITRE</a>"` <br/> conc. Of `H_(2)S = 0.125 <a href="https://interviewquestions.tuteehub.com/tag/mg-1095425" style="font-weight:bold;" target="_blank" title="Click to know more about MG">MG</a>.."litre"`</body></html> | |