1.

A piston filled with 0.04 mol of ideal gas expands reversibly from 50.0mL to 375 mLat a constant temperature of 37.0^(@)C. As it does so, itabsorbs 208J of heat. The value of q and w for the process will be : ( R= 8.314J // mol K , ln7.5 =2.01 )

Answer»

`Q= + 208 J , w= + 208 J`
`q = + 208 J , w = - 208 J`
` q = - 208 J , w= - 208 J`
`q = - 208 J, w= +208 J`

Solution :For isothermal EXPANSION of an ideal gas, `DeltaU = 0`. Hence,from FIRST law of thermodynamics, `DeltaU = q+w` , we have `q= -w` . As process INVOLVES adsorption of heat, i.e., it is endothermic `q= + 208 J:. W= - 208 J`


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