1.

A sample of 0.50 g of an organic compound was treated according to Kjeldahl's method. The ammonia evolved was absorbed in 50 mL of 0.5 M H_(2)SO_(4). The residual acid required 60 mL of 0.5 M solution of NaOH for neutralisation. What would be the percentage composition of nitrogen in the compound?

Answer»

50
60
56
44

Solution :Given:
Mass of compound taken=0.50g
VOL. of `H_(2)SO_(4)=50`mL
Molarity of `H_(2)SO_(4)=0.5M`
Vol. of NaOH required=60mL
Molarity of NaOH requried=0.5M
METHOD adopted Kjeldahl's method
Formula used: % of N`=(1.4xxMxx2[V-(V_(1))/(2)])/(m)`. .(i)
by substituting the vlaues in the formula, we GET
`%` of `N=(1.4xx0.5xx2(50-60//2))/(0.5)=56`
`therefore` % of N in the given compound=56%


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