1.

A solution containing Na_(2)CO_(3) and NaOH requires 300 mL of 0.1 N HCl using phenolphthalein as an indicator. Methyl orange is then added to above titrated solution when a further 25 mL of 0.2 N HCl is required. The amount of NaOH present in the original solution is :

Answer»

0.5 g
1 g
2 g
4 g

Solution :300 mL HCl of 0.1 N NEUTRALISES entire amount of NaOH and `1//2 " of" Na_(2)CO_(3)`. Remaining `1//2 " of " Na_(2)CO_(3)` is neutralised by 25 mL 0.2 N HCl, i.e., 50 mL of 0.1 N HCl.
THUS, 250 mL of 0.1 N HCl is required to neutralise NaOH completely.
`N_(1)V_(1)(NaOH)=N_(2)V_(2)(HCl)`
`=0.1xx250`
=25
`W_(NaOH)=(ENV)/(1000)=(40xx25)/(1000)=1 g`


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