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A solution contains 1 g mol. Each of p-toluene diazonium chloride and p-nitrophyenl diazonium chloride. To this 1g mol. Of alkaline of phenol is added. Predict the major product. Explain you answer.

Answer» <html><body><p></p>Solution :This reaction is an example of electrophilic <a href="https://interviewquestions.tuteehub.com/tag/aromatic-363924" style="font-weight:bold;" target="_blank" title="Click to know more about AROMATIC">AROMATIC</a> substitution. In alkaline <a href="https://interviewquestions.tuteehub.com/tag/medium-1092763" style="font-weight:bold;" target="_blank" title="Click to know more about MEDIUM">MEDIUM</a>, phenol generates phenoxide <a href="https://interviewquestions.tuteehub.com/tag/ion-1051153" style="font-weight:bold;" target="_blank" title="Click to know more about ION">ION</a> which is more electron rich than phenol and hence more reactive for electrophilic <a href="https://interviewquestions.tuteehub.com/tag/attack-887517" style="font-weight:bold;" target="_blank" title="Click to know more about ATTACK">ATTACK</a>. The electrophile ini this reaction is aryladizonium cation. Stronger the electrophile faster is the reaction. p Nitrophenyldiazonium cation is a stronger electrophile than p-toluene diazonium cation. Therefore, it couples preferntially with phenol. <br/> <img src="https://d10lpgp6xz60nq.cloudfront.net/physics_images/RES_CHM_AC_E01_018_S01.png" width="80%"/></body></html>


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