1.

A solution contains 25% water, 25% ethanol and 50% acetic acid by mass. Calculate the mole fraction of each component.

Answer»

SOLUTION :Suppose, we have 100 g of the GIVEN solution. Then,
mass of WATER = 25g mass of ethanol = 25 g and mass of acetic acid = 50 g.
The molecular MASSES of water, ethanol and acetic acid are 18, 46 and 60 RESPECTIVELY. Therefore,
number of moles of water `(n_(1)) = 25/18 = 1.39`
number of moles of ethanol `(n_(2)) = 25/46 = 0.54`
and number of moles of acetic acid `(n_(3)) = 50/60 = 0.83`
Total number of moles in solution = `n_(1) + n_(2) + n_(3) = 1.39 + 0.54 + 0.83 = 2.76`
Mole fraction of water = `n_(1)/(n_(1) + n_(2)+ n_(3))`
`=1.39/2.76 = 0.503`
Mole fraction of ethanol `=n_(2)/(n_(1) + n_(2) + n_(3))`
`=0.54/2.76 = 0.196`
Mole fraction of acetic acid = `n_(3)/(n_(1) + n_(2) + n_(3)) = 0.83/2.76 = 0.301`


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