1.

A solution cotaning 0.10 M in Ba(NO_(3))_(2) and 0.10 M in Sr(NO_(3))_(2). If solid Na_(2)CrO_(4) is added to the solution, what is [Ba^(2+)], when SrCrO_(4) beings to precipitate? [K_(sp)(BaCrO_(4)) = 1.2 xx 10^(-10), K_(sp) (SrCrO_(4)) = 3.5 xx 10^(-5)]

Answer»

`7.4 XX 10^(-7)`
`2.0 xx 10^(-7)`
`6.1 xx 10^(-7)`
`3.4 xx 10^(-7)`

Solution :`K_(SP)(SrCrO_(4)) = [Sr^(2+)][CrO_(4)^(2-)]`
`[CrO_(4)^(2-)] = (3.5 xx 10^(-5))/(0.1)= 3.5 xx 10^(-4)`
`K_(sp)(BaCrO_(4)) = [Ba^(2)][CrO_(4)^(2-)]`
`[CrO_(4)^(2-)]_("total") = [CrO_(4)^(2-)]` from `SrCrO_(4)`
`[Ba^(2+)] = (1.2 xx 10^(-10))/(3.5 xx 10^(-4)) = 3.4 xx 10^(-7)`


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