1.

A solution of Na_(2)S_(2)O_(3) is standardized iodometrically against 0.1262 g of KBrO_(3). This process required 45 mL of the Na_(2)S_(2)O_(3) solution. What is the strength of the Na_(2)S_(2)O_(3)? (K = 39, Br = 80)

Answer»

`0.2M`
`0.1M`
`0.05M`
`0.1N`

Solution :M.eq. `Na_(2)S_(2)O_(3)` = M.eq `I_(2)`
`45xxMxx1=nxx2impliesn=(45M)/(2)...(1)`
M.eq `I_(2)` = M.eq `KBrO_(3)`
`nxx2=6xx(0.1262)/(167)xx1000`
`impliesn=(3xx0.1262xx1000)/(167)...(2)`
From (1) & (2), `(45M)/(2)=(126.2xx3)/(167)impliesM=0.1`


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