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A sparingly soluble salt having general formula A_(x)^(p+) B_(y)^(q-) and molar solubility S is in equilibrium with its saturated solution. Derive a relationship between the solubility and solubility product for such salt.

Answer» <html><body><p>&lt;<a href="https://interviewquestions.tuteehub.com/tag/p-588962" style="font-weight:bold;" target="_blank" title="Click to know more about P">P</a>&gt;</p>Solution :Suppose molar solubility of `A_(<a href="https://interviewquestions.tuteehub.com/tag/x-746616" style="font-weight:bold;" target="_blank" title="Click to know more about X">X</a>)^(p+) B_(y)^(<a href="https://interviewquestions.tuteehub.com/tag/q-609558" style="font-weight:bold;" target="_blank" title="Click to know more about Q">Q</a>-)` is S mol `<a href="https://interviewquestions.tuteehub.com/tag/l-535906" style="font-weight:bold;" target="_blank" title="Click to know more about L">L</a>^(-1)`. Then <br/> `{:(A_(x)^(p+)B_(y)^(q-) ,hArr,x A^(p+),+ ,yB^(q-),,),(,,x S,,y S,,):}` <br/> `K_(sp) = [ A^(p+)]^(x) [B^(q-)]^(y)=[x S]^(x) [ y S ] ^(y)= x^(x) y^(y) S^(x+y)`</body></html>


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