1.

A swimmer coming out from a pool is covered with a film of water weighing about 18g. How much heat must be supplied to evaporate this water at 298 K? Calculate the internal energy of vaporisation at 100^@C. DeltaH_(vap)^@ for water at 373K = 40.66 kJ mol^(-1)

Answer»

Solution :We can represent the PROCESS of EVAPORATION as
`H_(2)O_((l)) overset("vaporisation")(rarr)H_2O_((g)) , DELTA = 1 - 0 = 1`
`Delta_(vap) E = Delta_(vap)H - pDeltaV =Delta_(vap) H - DeltanRT`
(assumig steam BEHAVING as an ideal gas).
`Delta_(vap) E = 40.66 kJ mol^(-1) - (1)`
`(8.314 xx 10^(-3) KJ K^(-1) mol^(-1))(373 K) = 37.56 kJ mol^(-1)`.


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