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A uni-univalment ionic crystal AX is composed of the following radii ( ar bitrary units) . {:( A^(+) , X^(-)),(1.0, 2.0):} Assuming that ions are hard spheres, predict giving reasons whether the crystal will have sodium chloride or cesium chloride structure.Calculate the volume of the unit cell. |
Answer» <html><body><p><br/></p>Solution : ` r_(+)//r_(-) = 2//1 = 0.5` Which lies in the range 0.414 - 0.732 <a href="https://interviewquestions.tuteehub.com/tag/hence-484344" style="font-weight:bold;" target="_blank" title="Click to know more about HENCE">HENCE</a>, it has sodium <a href="https://interviewquestions.tuteehub.com/tag/chloride-915854" style="font-weight:bold;" target="_blank" title="Click to know more about CHLORIDE">CHLORIDE</a> struture. <br/> ( <a href="https://interviewquestions.tuteehub.com/tag/edge-965664" style="font-weight:bold;" target="_blank" title="Click to know more about EDGE">EDGE</a> = ` 2 ( r_(+) + r_(-) = 6 "au"` . Volume =` ( 6 " au")^(3) = 216 ("au")^(3)`</body></html> | |