1.

A vessel contains a mixture of equal masses of helium and oxygen at a pressure of 600 torr. Calculate the partial pressures of components in the mixture.

Answer»

Solution :Let the mass of each component gas is x.
Total number of moles in the mixture =
`(XG " of " He)/(4G " of " mol^(-1)) + (xg " of " O_2)/(32 g " of " mol^(-1)) = (9x)/(32 g mol^(-1))`
Partial pressure = pressure of the mixture x mole FRACTION
Partial pressure of He `= 600 xx (x//4)/(9x//32) = 600 xx 8/9`
`= 5333.33"TORR"`
Partial pressure of `O_2 = 600 xx (x//32)/(9x//32)`
`= 600 xx 1/9 = 66.67` torr
(or) Partial pressure of `O_2 = 600 - 533.37 `
= 66.67 torr


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