1.

A vessel of 10L was filled with 6 mole of Sb_(2)S_(3) and 6 mole of H_(2) to attain the equilibrium at 440^(@)C as: Sb_(2)S_(3)(s)+3H_(2)(g)hArr2Sb(s)+3H_(2)S(g) After equilibrium the H_(2)S formed was analysed by dissolving it in water and treating with excess of Pb^(2+) to give 708 g "of" PbS as precipitate. What is value of K_(c) of the reaction at 440^(@)C?(At. weight of Pb=206).

Answer»

`0.08`
`0.8`
`0.4`
`0.04`

Solution :MOLE of `PbS=708//236="mole of" H_(2)S`
`Sb_(2)S_(3)(s)+3H_(2)(g)hArr2Sb(s)+3H_(2)S(g)`
`{:("Initial",6,6,0,0),("at EQ.",5,3,2,3):}`
`K_(c)=((3//10)^(3)xx(2//10)^(2))/((5//10)xx(3//10)^(3))=(4)/(50)=0.08`


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