1.

A white crystalline substance dissolves in hot water. On passing H_(2)S in this solution, black precipitate is obtained. The black precipitate dissolves completely in hot HNO_(3). On adding a few drops of conc. H_(2)SO_(4), a white precipitate is obtained. this substance is :

Answer»

`BaSO_(4)`
`SrSO_(4)`
`PbCl_(2)`
`CdSO_(4)`

Solution :White ppt is of `PbCl_(2)`. It dissolves in hot water
`PbCl_(2) + H_(2)S RARR underset(("Black ppt"))(PbS) + 2HCl`
PbS dissolves in hot conc. `HNO_(3)` and gives white ppt on adding conc. `H_(2)SO_(4)`


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