1.

According to Fajan rules , the percentage of covalent character in an ionic compound increases . If the cation is highly charged or the cation is small and the anion is large or the cation has pseudo inert gas configuration . As a result of increased covalent character , the melting point decreases and solubility in less polar solvent increases . The correct order of increasing ionic character is

Answer»

`BeCl_(2) lt MgCl_(2) lt CaCl_(2) lt BaCl_(2)`
`BeCl_(2) lt MgCl_(2) lt BaCl_(2) lt CaCl_(2)`
`BeCl_(2)lt BaCl_(2) lt MgCl_(2) lt CaCl_(2)`
`BaCl_(2) lt CaCl_(2) lt MgCl_(2) lt BeCl_(2)`

Solution :As the size of the CATION increases , electronegativity decreases but the electronegativity DIFFERENCE increases and hence IONIC CHARACTER increases accordingly , i.e., option (a) is correct .


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