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According to Fajan rules , the percentage of covalent character in an ionic compound increases . If the cation is highly charged or the cation is small and the anion is large or the cation has pseudo inert gas configuration . As a result of increased covalent character , the melting point decreases and solubility in less polar solvent increases . Based on lattice energy and other consideration , which one of the following alkali metal chlorides is expected to have the highest melting point ? |
Answer» <html><body><p>LiCl <br/>NaCl <br/>KCl <br/>RbCl . </p><a href="https://interviewquestions.tuteehub.com/tag/solution-25781" style="font-weight:bold;" target="_blank" title="Click to know more about SOLUTION">SOLUTION</a> :LiCl being <a href="https://interviewquestions.tuteehub.com/tag/covalent-427060" style="font-weight:bold;" target="_blank" title="Click to know more about COVALENT">COVALENT</a> has the lowest <a href="https://interviewquestions.tuteehub.com/tag/melting-1093090" style="font-weight:bold;" target="_blank" title="Click to know more about MELTING">MELTING</a> point . Among the remaining chlorides , because of <a href="https://interviewquestions.tuteehub.com/tag/smaller-1213327" style="font-weight:bold;" target="_blank" title="Click to know more about SMALLER">SMALLER</a> size of Na , NaCl has the highest lattice energy and hence has the highest melting point .</body></html> | |