Account for the following: t-butyl chloride reacts with aqueous KOH by S_(N)1 mechanism while n-butyl chloride reacts with S_(N^(2)) mechanism.

Account for the following: t-butyl chloride reacts with aqueous KOH by

1.	Account for the following: t-butyl chloride reacts with aqueous KOH by S_(N)1 mechanism while n-butyl chloride reacts with S_(N^(2)) mechanism.
Answer» <html><body><p></p>Solution :This is because rate of `S_(N(2))` <a href="https://interviewquestions.tuteehub.com/tag/reaction-22747" style="font-weight:bold;" target="_blank" title="Click to know more about REACTION">REACTION</a> is directly proportional to delta <a href="https://interviewquestions.tuteehub.com/tag/inversely-7688775" style="font-weight:bold;" target="_blank" title="Click to know more about INVERSELY">INVERSELY</a> proportional to steric crowding. Ter-buty & chloride has vast steric crowding. Ter-buty & chloride has vast steric crowding and <a href="https://interviewquestions.tuteehub.com/tag/thus-2307358" style="font-weight:bold;" target="_blank" title="Click to know more about THUS">THUS</a> it is more stable. For `S_(N^(1))` reaction rather then `S_(N^(2))` reaction.</body></html>