Addition of HBr to propene yields 2-bromo-propene, while in the presence of benzoyl peroxide, the same reaction yields 1-bromo-propane. Explain and give mechanism.

Addition of HBr to propene yields 2-bromo-propene, while in the presen

1.	Addition of HBr to propene yields 2-bromo-propene, while in the presence of benzoyl peroxide, the same reaction yields 1-bromo-propane. Explain and give mechanism.
Answer» <html><body><p></p><a href="https://interviewquestions.tuteehub.com/tag/solution-25781" style="font-weight:bold;" target="_blank" title="Click to know more about SOLUTION">SOLUTION</a> :(a) Addition to <a href="https://interviewquestions.tuteehub.com/tag/hbr-479388" style="font-weight:bold;" target="_blank" title="Click to know more about HBR">HBR</a> to propene, yields 2-bromo-propane and it is electrophilic addition reaction. <br/> (<a href="https://interviewquestions.tuteehub.com/tag/b-387190" style="font-weight:bold;" target="_blank" title="Click to know more about B">B</a>) Addition to Hbr to propene in <a href="https://interviewquestions.tuteehub.com/tag/presence-25557" style="font-weight:bold;" target="_blank" title="Click to know more about PRESENCE">PRESENCE</a> of peroxide, forms 1-bromopropane, it is free-radical addition reaction.</body></html>