1.

Addition of sulphuric acid in alkene and addition of sulphuric acid in alkene with addition reaction.

Answer»

SOLUTION :Dissociation of sulphuric acid `(H_(2)SO_(4) hArr H^(DELTA+)O^(delta-)SO_(3)H)` fragement are `H^(delta+)` and `HSO_(4)^(-)` or `""^(-)OSO_(3)H` positive and negative radicals on `pi`-bond as per Markovnikov rule electrophilic ADDITION reaction.
(i) `H_(2)SO_(4) rarr overset(+)(H)+bar(O)SO_(2)OH`

(ii) Propene is reacted with`H_(2)SO_(4)` where `overset(+)(H)` is electrophilic species. More stable carbocation `CH_(3)overset(+)(C)HCH_(3)` is formed first, negative part hydrogen sulfate, is added as addition product and formed ISOPROPYL hydrogen sulphare.

This reaction occurs at normal temperature and ractants are added in ratio 1:1 and formation of alkyl hydrogen sulpare.


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