1.

Alkali and alkaline earth metals along with hydrogen and helium constitute s-block elements . They have low ionization enthalpies and hence exhibit characteristic flame colouration . They have highly negative electrode potentials and hence are strong reducing agents . Their solutions in liquid ammonia are conducting and also act as strong reducing agents than hydrogen , they are usually prepared by electrolysis of their fused chlorides . Their oxides are basic and the basic strength increases down the group . The solubility of carbonates and sulphates of alkali and alkaline earth metals show opposite trends . The carbonates of alkaline earth metals and lithium carbonate decompose on heating while the carbonates of other alkali metals do not decompose on heating . The bicarbonates of both alkali and alkaline earth metals on heating give carbonates . The basic character of the oxides , MgO , SrO , K_(2)O , NiO and Cs_(2)O increases in the order :

Answer»

`MGO gt Sr O gt K_(2)O gt NIO gt Cs_(2)`
`Cs_(2) lt K_(2)O lt MgO lt SrO lt NiO`
`NiO lt MgO lt SrO lt K_(2)O lt Cs_(2)O`
`K_(2)O ltNiO lt MgO lt SrO lt Cs_(2)`

Solution :Alkali metal OXIDES are most basic followed by alkaline earth metal oxides while transition metal oxides are LEAST basic . Amongst alkali and alkaline earth metal oxides , basicity increases down the group . Thus , `Cs_(2)O` is more basic than `K_(2)O` and `SrO` is more basic than MgO . therefore , the overall order is `: NiO lt MgO lt SrO lt K_(2)O lt Cs_(2)O`.


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