1.

Alkaline earth metals always form divalent cations even through their second ionization enthalpies are almost double than their first ionization enthalpies . Explain .

Answer»

Solution :In the solid state , higher enthalpy of lattice formationby `M^(2+)` ions (as compared to `M^(+)`ions) more than compensates the higher SECOND ionization enthalpies of METALS and in AQUEOUS solution , higher enthalpy of HYDRATION of `M^(2+)` ions (as compared to `M^(+)` ions) more than compensates the higher second ionization enthalpy


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