1.

Ammonium carbamate when heated to 200^(@) Cgives a mixture of NH_(3) and CO_(2) vapours with a density of 16*0 . What is the degree of disociation of ammonium carbamate ?

Answer»

`3//2`
`1//2`
2
1

Solution :`{: (,NH_(2)COONH_(4),to,2NH_(3),+,CO_(2)), ("Intial" ,1"mole",,,,), ("After disso.",1-alpha,,2ALPHA,,alpha ),(,,,,,"Total"=1+2 alpha):}`
Theoretical density `(D) propto 1/V `
OBSERVED density ` (d) propto 1/((1+2alpha)V)`
` :. D/d = 1+ 2 alpha `
or ` alpha = 1/2 ((D-d)/d) = 1/2 ((48-16*0)/16*0) =1*0 `


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