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Among the following the dissociation constant is highest forA. `C_(6)H_(5)OH`B. `C_(6)H_(5)CH_(2)OH`C. `CH_(3)C-=CH`D. `CH_(3)NH_(3)^(+)Cl^(-)` |
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Answer» Correct Answer - D Dissociation of proton from `CH_(3)-overset(+)(N)H_(3)Cl^(-)` is very difficult due to -I effect of `Cl^(-)` and `N^(+)` while in `C_(6)H_(5)OH` due to resonance stabilization of phenoxide ion proton eliminate easily similarly due to H-bonding in `C_(6)H_(5)CH_(2)OH` it can be eliminated and `CH_(3)C-=CH` show acidic character by triple bond by which proton can be dissociate. |
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