1.

Amongst `[TiE_(6)]^(2-), [CoF_(6)]^(3-), Cu_(2)Cl_(2)` and `[NiCl_(4)]^(2-)` [Atomic no. `Ti = 22, Co = 27, Cu = 29, Ni = 28`] the colourless species are : (A) `[TiF_(6)]^(2-)` and `[Cu_(2)Cl_(2)]` (B) `Cu_(2)Cl_(2)` and `[NiCl_(4)]^(2-)` (C) `[TiF_(6)]^(2-)` and `[CoF_(6)]^(3-)` (D) `[CoF_(6)]^(3-)` and `[NiCl_(4)]^(2-)`A. `COF_(6)^(3-) and NiCl_(4)^(2-)`B. `TiF_(6)^(2-) and COF_(6)^(3-)`C. `Cu_(2)Cl_(2) and NiCl_(4)^(2-)`D. `TiF_(6)^(2-) and Cu_(2)Cl(2)`

Answer» Correct Answer - D
Transition metal ions having unpaired electrons are coloured while those which those which have no unpaired electron are colourless
In `TiF_(6)^(2-),Ti^(4+):[Ar]3d^(0),0` unpaired electron, colourless
In `Cu_(2)Cl_(2),Cu^(+):[Ar]3d^(10),0` unpaired electrons, colourless
In`COf_(6)^(3-),CO^(3+):[Ar]3d^(6),4`
In` NiCl_(4)^(2-), Ni^(2+):[Ar]3d^(8),2` unpaired electrons, coloured


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