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Answer the following questions briefly: (i). What is the actual reducing agent of haematite in blast furnace? (ii). Zinc, not copper is used for the recovery of metallic silver from the complex `[Ag(CN)_2]^(ɵ)`, explain. (iii). Why is chalcocite roasted and not calcinated during the recovery of copper? |
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Answer» (i). For iron, first by calcination and roasting the ferrous oxide is oxidised to ferric. Then in blast furnace, Smelting is done where it is reduced to iron. `4FeO+O_2to2Fe_2O_3` `Fe_2O_3+COto2Fe_3O_4+CO_2` `Fe_2O_3+COto2FeO+CO_2` `FeO+COtoFe+CO_2` Carbon monoxide is the actual reducing agent of haematite in blast furnace. (ii). Zinc is more reducing and cheaper than copper. (iii). Chalcocite is a sulphide ore of copper therefore it must be roasted in the presence of air to get oxide. |
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