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Assertion: Each vibrational mode gives two degrees of freedom. Reason: By law of equipartition of energy, the energy for each degree of freedom in thermal equlibrium is 2k_(B)T. |
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Answer» If both assertion and reason are true and reason is the correct EXPLANATION os assertion. Each QUADRATIC term from in the total energy rxpression of a molecules is to be conunted as a degree of freedom. Thus each vibriational mode gives 2 degrees of freedom i.e., kinetic and potential energy modes, corresponding to the energy `2((1)/(2)k_(BT))=k_(B)T.` |
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