1.

At what pH of HCl solution, will hydrogen gas electrode show electrode potential of -0.118 V ? `H_(2)` gas is bubbled at 298 K and 1 atm pressure.

Answer» Correct Answer - pH=2
`H^(+)+e^(-) to 1//2H_(2)`
`E_(cell)=E_(cell)^(@)-(0.0591)/(1)"log"(1)/([H^(+)])`
`-0.188=0-0.0591 " pH" " "(because pH="log "1//[H^(+)])`
`pH=(0.118)/(0.0591)=2`.


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