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Calculate the effective nuclear charge at the periphery of nitrogen atom when an extre electron is added in the formation of anion . Also calculate the effective nuclear charge of N-atom. |
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Answer» Ground state electron configuration of N(Z=7)=`1s^(2)2s^(2)2p^(3)` Electron configuration of `N^(-)=(1s^(2))(2s^(2)2p^(4))` Shielding constant for the last 2p electron, `sigma=[(2xx0.85)+(5xx0.35)]=3.45` So `Z_(eff)=Z-sigma=7-3.45=3.55` Electron configuration of `N^(+)=(1s^(2))(2s^(2)2p^(2))` Shielding constant for the last 2p electron, `sigma=[(2xx0.85)+(3xx0.35)]=2.75` So `Z_(eff)` for the last electron on `N^(+)=7-2.75=4.25` |
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