InterviewSolution
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InterviewSolution
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Compound A releases an inert gas with `HNO_2` form isocyanate with `(HgCl_2)/(CS_2)` and a solid with diethyl oxalate. It can beA. an optically active compound containing three C-atomsB. A compound formed by the reduction product of reaction of `AgNC(alc)` with RCl.C. A compound having `-NH_2` group at carbonyl carbon.D. a compound which is formed by acylazide in alkaline medium. |
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Answer» Correct Answer - D `1^@` amines gives `N_2` (inert gas) with `HNO_2` and forms isocyanate with `(HgCl_2)/(CS_2)` and a solid `(N,N]`-dialkyl oxamide) with diethyl oxalate. Thus, it can be (a). `CH_(3)underset(NH_(2))underset(|)(C)HCH_(3)` (optically inactive) (b). `RCloverset(AgCN)toRNCoverset("Reduction")tounderset(2^(@)" amine")(RNHCH_(3))` (c). `R-overset(O)overset(||)(C)-N_(3)underset(-Na_(2)CO_(3))overset(OH^(-))tounderset(1^(@)"amine")(RNH_(2))` (d). `R-overset(O)overset(||)(C)-NH_(2)` (compound with `-NH_(2)` at carbonyl carbon) |
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